Organic Chemistry 2 Reactions Flashcards
ALKENE REACTIONS
ALKENE REACTIONS
Hydration: Reagants
Strong Acid, H20
Hydration: Products
Alcohol (Regioselective: Markovnikof)
Oxymercuration/Demercuration: Reagents
1. Hg(OAc)2, H2O 2. NaBh4, NaOH
Oxymercuration/Demercuration: Products
Alcohol (Regioselective: Markovnikof)
Addition of a Hydrogen Halide: Products
Alkyl Halide (Regioselective: Markovnikof)
Hydrogenation: Reagents
H2, Pt
Hydrogenation: Products
Alkane (Stereospecific: Syn)
Cyclopropanation: Reagents
Carbene
Cyclopropanation: Products
Cyclopropane (Stereospecific: Syn)
Epoxidation: Reagents
mCPBA
Epoxidation: Products
Epoxide (Stereospecific: Syn)
Acid-Catalzyed Epoxide Ring Opening: Products
Diol (Stereospecific: Anti) (A diol contains two hydroxyl groups)
Syn-Dihydroxylation: Reagents
OsO4, H2O2
Syn-Dihydroxylation: Products
Diol (Stereospecific: syn)
Formation of a Halohydrin: Products
Halohydrin ( functional group in which a halogen and a hydroxyl are bonded to adjacent carbon atoms)(Stereospecific: Anti) (Regioselective: Mark addition of -OH)
Addition of X2: Products
Vicinal Dihalde (Stereospecific: Anti)
Addition of HBr and Peroxides: Reagents
HBr, H2O2
Addition of HBr and Peroxides: Products
Alkyl Bromide (Regioselective: Anti-Mark)
Hydroboration/Oxidation: Products
Alcohol Stereospecific: Syn) (Regioselective: Anti-Mark)
Oxidative Cleavage: Reagents
KMnO4, Base
Oxidative Cleavage: Products
Ketones and Carboxylic Acids
Ozonolysis, Reductive: Reagents
O3, Me2S
Ozonolysis, Reductive: Products
Ketones and Aldehydes
Ozonolysis, Oxidative: Reagents
H2O2, AcOH
Ozonolysis, Oxidative: Products
Ketones and Carboxylic Acids
Grignard: Reagents
a. Mg, Ether b. Carbonyl c. strong acid ORa. LI Alkane, Ether b. Carbonyl c. strong acid
Grignard: Products
Alcohol(Regioselective: Reagent adds to the Carbonyl)
ALKYNE REACTIONS
ALKYNE REACTIONS
Synthesis of Dihalides: Reagents
NaOH, 200C OR NaNH3, H20
Acetylide Anion: Reagents
Strong Nucleophile, H20
Acetylide Anion: Products
Alcohol
Oxidation of an Internal Alkyne: Reagents
KMnO4, H2O
Oxidation of an Internal Alkyne: Products
Dicarbonyl
Oxidation of an Terminal Alkyne: Reagents
KMnO4, H2O
Oxidation of an Terminal Alkyne: Products
Carboxylic Acid with adjacent Ketone
Hydrogenation (Alkyne): Products
Cis Alkene (Stereospecific: Syn)
Dissolving Metal Reduction: Reagents
Na(s), NH3, low temp
Dissolving Metal Reduction: Products
Trans Alkene (Stereospecific: Anti)
Ozonolysis: Reagents
O3, H2O
Ozonolysis: Products
Carboxylic Acids
Addition of HBr with Peroxides: Reagents
HBr, H2O2
Addition of HBr with Peroxides: Products
Vinyl Bromide (Regioselective: Mark)
Addition of X2 (Alkyne): Reagents
X2, CH2Cl2
Addition of X2 (Alkyne): Products
Dohalide/Tetrahalide (Stereospecific: Anti)
Addition of HX: Reagents
HX, Ch2Cl2
Addition of HX: Products
Dihalide/Tetrahalide (Regioselective: Mark)
Hydration (Alkyne): Reagents
HgSO4, H2SO4
Hydration (Alkyne): Products
Ketone(Regioselective: Mark)
Hydroboration/Oxidaton: Reagents
SiaBH, H20, Strong Base
Hydroboration/Oxidaton: Products
Aldehyde(Regioselective: Anti-Mark)